The sun emits light waves with a range of frequencies. Some of these frequencies fall within the visible light spectrum and thus are detectable by the human eye. Since sunlight consists of light with the range of visible light frequencies, it appears white. This white light is incident towards Earth and illuminates both our outdoor world and the atmosphere that surrounds our planet. As discussed earlier in Lesson 2, the interaction of visible light with matter will often result in the absorption of specific frequencies of light. The frequencies of visible light that are not absorbed are either transmitted (by transparent materials) or reflected (by opaque materials). As we sight at various objects in our surroundings, the color that we perceive is dependent upon the color(s) of light that are reflected or transmitted by those objects to our eyes. So if we consider a green leaf on a tree, the atoms of the chlorophyll molecules in the leaf are absorbing most of the frequencies of visible light (except for green) and reflecting the green light to our eyes. The leaf thus appears green. And as we view the black asphalt street, the atoms of the asphalt are absorbing all the frequencies of visible light and no light is reflected to our eyes. The asphalt street thus appears black (the absence of color). In this manner, the interaction of sunlight with matter contributes to the color appearance of our surrounding world. In this part of Lesson 2, we will focus on the interaction of sunlight with atmospheric particles to produce blue skies and red sunsets. We will attempt to answer these two questions:

• Why are the skies blue?
• Why are the sunsets red?

Why are the skies blue?

The interaction of sunlight with matter can result in one of three wave behaviors: absorption, transmission, and reflection. The atmosphere is a gaseous sea that contains a variety of types of particles; the two most common types of matter present in the atmosphere are gaseous nitrogen and oxygen. These particles are most effective in scattering the higher frequency and shorter wavelength portions of the visible light spectrum. This scattering process involves the absorption of a light wave by an atom followed by reemission of a light wave in a variety of directions. The amount of multidirectional scattering that occurs is dependent upon the frequency of the light. (In fact, it varies according to f⁴.) Atmospheric nitrogen and oxygen scatter violet light most easily, followed by blue light, green light, etc. So as white light (ROYGBIV) from the sun passes through our atmosphere, the high frequencies (BIV) become scattered by atmospheric particles while the lower frequencies (ROY) are most likely to pass through the atmosphere without a significant alteration in their direction. This scattering of the higher frequencies of light illuminates the skies with light on the BIV end of the visible spectrum. Compared to blue light, violet light is most easily scattered by atmospheric particles. However, our eyes are more sensitive to light with blue frequencies. Thus, we view the skies as being blue in color.

Why are sunsets red?

Meanwhile, the light that is not scattered is able to pass through our atmosphere and reach our eyes in a rather non-interrupted path. The lower frequencies of sunlight (ROY) tend to reach our eyes as we sight directly at the sun during midday. While sunlight consists of the entire range of frequencies of visible light, not all frequencies are equally intense. In fact, sunlight tends to be most rich with yellow light frequencies. For these reasons, the sun appears yellow during midday due to the direct passage of dominant amounts of yellow frequencies through our atmosphere and to our eyes.

 

The appearance of the sun changes with the time of day. While it may be yellow during midday, it is often found to gradually turn color as it approaches sunset. This can be explained by light scattering. As the sun approaches the horizon line, sunlight must traverse a greater distance through our atmosphere; this is demonstrated in the diagram below.

 

As the path that sunlight takes through our atmosphere increases in length, ROYGBIV encounters more and more atmospheric particles. This results in the scattering of greater and greater amounts of yellow light. During sunset hours, the light passing through our atmosphere to our eyes tends to be most concentrated with red and orange frequencies of light. For this reason, the sunsets have a reddish-orange hue. The effect of a red sunset becomes more pronounced if the atmosphere contains more and more particles. The presence of sulfur aerosols (emitted as an industrial pollutant and by volcanic activity) in our atmosphere contributes to some magnificent sunsets (and some very serious environmental problems).